Ayodele is from Nigeria and attended Ijapo Estate Primary School, Akure between 1991 and 1996 and later Christ School, Ado-Ekiti where he was awarded a National Mathematics Award in 2001 before graduating in 2003. He earned his bachelor's degree in Civil Engineering from the Ladoke Akintola University of Technology, Ogbomoso in 2010 and secured the Orange Knowledge Program scholarship in 2019 for his master's degree in Water Science & Engineering from IHE Delft, the Netherlands graduating in 2021. Ayodele has been working with the Nigeria Hydrological Services Agency where his efforts have contributed to improving rural/urban water supply, enhancing food security, adopting better strategies for environmental management, and enhancing data-driven surface/groundwater monitoring useful for effective flood management, infrastructural development, and water resources development in Nigeria. Ayodele is keenly interested in water policy for sustainable management. Ayodele is an Aig-Imoukhuede Foundation (AIG) Scholar.